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Supercritical extraction of biomass-A green and sustainable method to control the pyrolysis product distribution

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dc.contributor.author Trubetskaya, Anna
dc.contributor.author Attard, Thomas M.
dc.contributor.author Budarin, Vitaliy L.
dc.contributor.author Hunt, Andrew J.
dc.contributor.author Arshadi, Mehrdad
dc.contributor.author Grams, Jacek
dc.date.accessioned 2021-04-06T10:24:49Z
dc.date.issued 2021
dc.identifier.uri http://hdl.handle.net/10344/9961
dc.description peer-reviewed en_US
dc.description The full text of this article will not be available until the embargo expires on the 01/04/2022
dc.description.abstract This research demonstrates that supercritical extraction of the biomass has a remarkable and complex influence on Scots pine tree fractions changing the surface concentration of water, lipids, and metals simultaneously. Surprisingly, this surface composition modification makes a considerable impact on the pyrolysis of the bulk biomass mechanism, leading to the alternation of the volatile and inorganic matter composition. The unique combination of time-of-flight secondary-ion mass spectrometry analysis and utilization of pyrolysis gas chromatography−mass spectrometry data on the thermal behavior of woody biomass demonstrates, for the first time, the extraordinary influence of surface adsorbed metals on the composition of pyrolysis products. ScCO2 could extract the surface metals in the form of fatty acid salts, demonstrating a sustainable and environmentally friendly pretreatment method for controlling the pyrolysis products. en_US
dc.language.iso eng en_US
dc.publisher American Chemical Society en_US
dc.relation.ispartofseries ACS Sustainable Chemistry & Engineering; 9 (15), pp. 5278-5287
dc.relation.uri https://doi.org/10.1021/acssuschemeng.0c08599
dc.rights This is the author's version of the work. It is posted here by permission of ACM for your personal use. Not for redistribution. The definitive version was published in ACS Sustainable Chemistry & Engineering , https://doi.org/10.1021/acssuschemeng.0c08599
dc.subject supercritical extraction en_US
dc.subject surface en_US
dc.subject metal cations en_US
dc.subject Scots pine en_US
dc.title Supercritical extraction of biomass-A green and sustainable method to control the pyrolysis product distribution en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1021/acssuschemeng.0c08599
dc.date.embargoEndDate 2022-04-01
dc.embargo.terms 2022-04-01 en_US
dc.rights.accessrights info:eu-repo/semantics/embargoedAccess en_US


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