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Supercritical extraction and microwave activation of wood wastes for enhanced syngas production and generation of fullerene-like soot particles

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dc.contributor.author Trubetskaya, Anna
dc.contributor.author Hunt, Andrew J.
dc.contributor.author Budarin, Vitaliy L.
dc.contributor.author Attard, Thomas M.
dc.contributor.author Kling, Jens
dc.contributor.author Surup, Gerrit Ralf
dc.contributor.author Arshadi, Mehrdad
dc.contributor.author Umekigi, Kentaro
dc.date.accessioned 2020-10-16T09:07:50Z
dc.date.available 2020-10-16T09:07:50Z
dc.date.issued 2020
dc.identifier.uri http://hdl.handle.net/10344/9341
dc.description peer-reviewed en_US
dc.description.abstract This work demonstrated that supercritical carbon dioxide extraction is effective as a pre-treatment technology to generate soot particles with the fullerene-like structure and increase syngas yield from extracted residues during coupled microwave activation with gasification. Supercritical carbon dioxide extraction removes over half of the fatty and resin acids from needles and branches, whereas the extraction of needles generates greater yields of value-added compounds. The high yields of extractives indicate the effective conversion of waste wood for the sustainable production of value-added chemicals. The wood extraction did not influence the solid residue yields during pyrolysis/gasification emphasizing the significant potential of integrating the extraction process into the holistic biorefinery. Interestingly, supercritical carbon dioxide extraction had a significant effect on the structure and quality of soot particles formed. The differences in the extractives composition led to the formation of needle soot particles with a porous and less ordered nanostructure, whereas the soot branches obtained a ring graphitic structure. The greater yields of steroids and terpenes during the extraction of needles compared to the branches pretreatment indicated the influence of the extractives type on the soot nanostructure en_US
dc.language.iso eng en_US
dc.publisher Elsevier en_US
dc.relation CETEX en_US
dc.relation.ispartofseries Fuel Processing Technology;212, 106633
dc.subject carbon dioxide en_US
dc.subject biomass en_US
dc.subject biorefinery en_US
dc.subject nanomaterials en_US
dc.title Supercritical extraction and microwave activation of wood wastes for enhanced syngas production and generation of fullerene-like soot particles en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1016/j.fuproc.2020.106633
dc.contributor.sponsor Kempe Foundation en_US
dc.contributor.sponsor Thailand Research Fund en_US
dc.contributor.sponsor Khon Kaen University en_US
dc.contributor.sponsor Ministry of Higher Education, Science, Research and Innovation en_US
dc.relation.projectid RSA6280031 en_US
dc.rights.accessrights info:eu-repo/semantics/openAccess en_US


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