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Recent advancement of ullmann condensation coupling reaction in the formation of aryl-oxygen (C-O) bonding by copper-mediated catalyst

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dc.contributor.author Fui, Choong Jian
dc.contributor.author Sarjadi, Mohd Sani
dc.contributor.author Sarkar, Shaheen M.
dc.contributor.author Rahman, Md Lutfor
dc.date.accessioned 2020-10-08T07:49:13Z
dc.date.available 2020-10-08T07:49:13Z
dc.date.issued 2020
dc.identifier.uri http://hdl.handle.net/10344/9306
dc.description peer-reviewed en_US
dc.description.abstract Transition metal-catalyzed chemical transformation of organic electrophiles and organometallic reagents belong to the most important cross coupling reaction in organic synthesis. The biaryl ether division is not only popular in natural products and synthetic pharmaceuticals but also widely found in many pesticides, polymers, and ligands. Copper catalyst has received great attention owing to the low toxicity and low cost. However, traditional Ullmann-type couplings suffer from limited substrate scopes and harsh reaction conditions. The introduction of homogeneous copper catalyst with presence of bidentate ligands over the past two decades has totally changed this situation as these ligands enable the reaction promoted in mild condition. The reaction scope has also been greatly expanded, rendering this copper-based cross-coupling attractive for both academia and industry. In this review, we will highlight the latest progress in the development of useful homogeneous copper catalyst with presence of ligand and heterogeneous copper catalyst in Ullmann type C-O cross-coupling reaction. Additionally, the application of Ullmann type C-O cross coupling reaction will be discussed. en_US
dc.language.iso eng en_US
dc.publisher MDPI en_US
dc.relation GUG0382-1/2019 en_US
dc.relation.ispartofseries catalysts;10, 1103
dc.subject Ullmanncross-coupling en_US
dc.subject homogeneous catalyst en_US
dc.title Recent advancement of ullmann condensation coupling reaction in the formation of aryl-oxygen (C-O) bonding by copper-mediated catalyst en_US
dc.type info:eu-repo/semantics/article
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.3390/catal10101103
dc.contributor.sponsor University Malaysia Sabah en_US
dc.relation.projectid GUG0382-1/2019 en_US
dc.rights.accessrights info:eu-repo/semantics/openAccess en_US


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