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Metal–organic material polymer coatings for enhanced gas sorption performance and hydrolytic stability under humid conditions

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dc.contributor.author Madden, David G.
dc.contributor.author Albadarin, Ahmad B.
dc.contributor.author O'Nolan, Daniel
dc.contributor.author Cronin, Patrick
dc.contributor.author Perry, John J.
dc.contributor.author Solomon, Samuel
dc.contributor.author Curtin, Teresa
dc.contributor.author Khraisheh, Majeda
dc.contributor.author Zaworotko, Michael J.
dc.contributor.author Walker, Gavin M.
dc.date.accessioned 2020-07-27T10:14:00Z
dc.date.issued 2020
dc.identifier.uri http://hdl.handle.net/10344/9043
dc.description peer-reviewed en_US
dc.description The full text of this article will not be available in ULIR until the embargo expires on the 04/06/2021
dc.description.abstract Physisorbent metal–organic materials (MOMs) have shown benchmark performance for highly selective CO2 capture from bulk and trace gas mixtures. However, gas stream moisture can be detrimental to both adsorbent performance and hydrolytic stability. One of the most effective methods to solve this issue is to transform the adsorbent surface from hydrophilic to hydrophobic. Herein, we present a facile approach for coating MOMs with organic polymers to afford improved hydrophobicity and hydrolytic stability under humid conditions. The impact of gas stream moisture on CO2 capture for the composite materials was found to be negligible under both bulk and trace CO2 capture conditions with significant improvements in regeneration times and energy requirements. en_US
dc.language.iso eng en_US
dc.publisher American Chemical Society en_US
dc.relation 15SIRG3552 en_US
dc.relation.ispartofseries ACS Applied Materials and Interfaces;
dc.relation.uri https://doi.org/10.1021/acsami.0c08078
dc.rights © Year ACS This document is the Accepted Manuscript version of a Published Work that appeared in final form inACS Applied Materials and Interfaces , copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsami.0c08078 en_US
dc.subject ultramicroporous materials en_US
dc.subject carbon dioxide en_US
dc.subject adsorption en_US
dc.subject separation en_US
dc.subject polymer coating en_US
dc.title Metal–organic material polymer coatings for enhanced gas sorption performance and hydrolytic stability under humid conditions en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1021/acsami.0c08078
dc.contributor.sponsor SFI en_US
dc.relation.projectid 12/RC/2275-P2 en_US
dc.relation.projectid 12/RI/2345 en_US
dc.relation.projectid 13/IA/1980 en_US
dc.relation.projectid 15/SIRG/3552 en_US
dc.relation.projectid 13/RP/B2549 en_US
dc.date.embargoEndDate 2021-06-04
dc.embargo.terms 2021-06-04 en_US
dc.rights.accessrights info:eu-repo/semantics/embargoedAccess en_US


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