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Fine tuning and specific binding sites with a porous hydrogen-bonded metal-complex framework for gas selective separations

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dc.contributor.author Bao, Zongbi
dc.contributor.author Xie, Danyan
dc.contributor.author Chang, Ganggang
dc.contributor.author Wu, Hui
dc.contributor.author Li, Liangying
dc.contributor.author Zhou, Wei
dc.contributor.author Wang, Hailong
dc.contributor.author Zhang, Zhiguo
dc.contributor.author Xing, Huabin
dc.contributor.author Yang, Qiwei
dc.contributor.author Zaworotko, Michael J.
dc.contributor.author Ren, Qilong
dc.contributor.author Chen, Banglin
dc.date.accessioned 2019-11-28T15:33:38Z
dc.date.available 2019-11-28T15:33:38Z
dc.date.issued 2018
dc.identifier.uri http://hdl.handle.net/10344/8273
dc.description peer-reviewed en_US
dc.description.abstract Research on HOFs has been developed for quite a long time; however, those with both established permanent porosities and functional properties are extremely rare due to weak hydrogen-bonding interactions among molecular organic linkers which are much more fragile and difficult to stabilize. Herein, through judiciously combining the superiority of both the moderately stable coordination bonds in MOFs and hydrogen bonds, we have realized a microporous hydrogenbonded metal-complex or metallotecton framework HOF-21, which not only shows permanent porosity but also exhibits highly selective separation performance of C2H2/C2H4 at room temperature. The outstanding separation performance can be ascribed to sieving effect confined by the fine-tuning pores and the superimposed hydrogen-bonding interaction between C2H2 and SiF62- on both ends as validated by both modeling and neutron powder diffraction experiments. More importantly, the collapsed HOF-21 can be restored by simply immersing it into water or salt solution. To the best of our knowledge, such extraordinary water stability and restorability of HOF-21 was observed for the first time in HOFs, underlying the bright perspective of such new HOF materials for their industrial usage. en_US
dc.language.iso eng en_US
dc.publisher American Chemical Society en_US
dc.relation.ispartofseries Journal of the American Chemical Society;140 (13), pp. 4596-4603
dc.relation.uri http://dx.doi.org/10.1021/jacs.7b13706
dc.rights © 2018 ACS This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/jacs.7b13706 en_US
dc.subject novel porous materials en_US
dc.subject gas separations en_US
dc.title Fine tuning and specific binding sites with a porous hydrogen-bonded metal-complex framework for gas selective separations en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1021/jacs.7b13706
dc.contributor.sponsor Zhejiang Provincial Natural Science Foundation of China en_US
dc.contributor.sponsor National Natural Science Foundation of China en_US
dc.relation.projectid 2016YFB0301500 en_US
dc.relation.projectid 21722609 en_US
dc.relation.projectid 21436010 en_US
dc.relation.projectid AX-1730 en_US
dc.relation.projectid DMR-1606826 en_US
dc.rights.accessrights info:eu-repo/semantics/openAccess en_US


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