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Template-directed synthesis of photocatalyst-encapsulating metal-organic frameworks with boosted photocatalytic activity

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dc.contributor.author Yang, Xiaojie
dc.contributor.author Liang, Tao
dc.contributor.author Sun, Jiaxing
dc.contributor.author Zaworotko, Michael J.
dc.contributor.author Chen, Yao
dc.contributor.author Cheng, Peng
dc.contributor.author Zhang, Zhenjie
dc.date.accessioned 2019-10-07T10:27:27Z
dc.date.issued 2019
dc.identifier.uri http://hdl.handle.net/10344/8108
dc.description peer-reviewed en_US
dc.description The full text of this article will not be available in ULIR until the embargo expires on the 10/07/2020
dc.description.abstract In the past decade, the use of visible light to promote organic transformations has gained intense attention. In this study, we developed a template-directed synthesis method to use homogenous Ru and Ir photocatalysts as structure-directing templates and succeeded to prepare a series of photocatalyst-encapsulating metal-organic frameworks (photocatalyst@MOFs) with zeolite-like structures. The open channels and polyhedral cages of MOFs allowed effectively disperse the encapsulated photocatalysts and facilitated the transport of reactants and products, leading to boosted catalytic activity and good reusability toward important organic reactions such as aerobic oxidation reaction of benzyl halides and the cyclization of tertiary anilines and maleimides under visible light. Moreover, we also demonstrate the versatility and universality of our templating strategy. It not only can form MOFs which cannot be accessed by other synthesis methods, but also can encapsulate various commercially available homogeneous photocatalysts into MOFs. This work explores a avenue to prepare heterogeneous photocatalysts to catalyze value-added reactions en_US
dc.language.iso eng en_US
dc.publisher American Chemical Society en_US
dc.relation.ispartofseries ACS Catalysis;9 (8),pp. 7486-7493
dc.relation.uri http://dx.doi.org/10.1021/acscatal.9b01783
dc.rights © 2019 ACS This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acscatal.9b01783 en_US
dc.subject visible light en_US
dc.subject template-directed synthesis en_US
dc.subject photocatalyst en_US
dc.subject metal-organic framework en_US
dc.subject aerobic oxidation en_US
dc.title Template-directed synthesis of photocatalyst-encapsulating metal-organic frameworks with boosted photocatalytic activity en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1021/acscatal.9b01783
dc.contributor.sponsor National Natural Science Foundation of China en_US
dc.contributor.sponsor Tianjin Natural Science Foundation of China en_US
dc.relation.projectid 21601093 en_US
dc.relation.projectid 18JCZDJC37300 en_US
dc.date.embargoEndDate 2020-07-10
dc.embargo.terms 2020-07-10 en_US
dc.rights.accessrights info:eu-repo/semantics/embargoedAccess en_US


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