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A mixed molecular salt of lithium and sodium breaks the Hume-Rothery rules for solid solutions

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dc.contributor.author Lestari, Monica
dc.contributor.author Lusi, Matteo
dc.date.accessioned 2019-03-06T12:32:33Z
dc.date.available 2019-03-06T12:32:33Z
dc.date.issued 2019
dc.identifier.uri http://hdl.handle.net/10344/7659
dc.description peer-reviewed en_US
dc.description.abstract The first molecular solid solution of lithium and sodium ions is reported. In spite of the different chemical and structural properties of the parent compounds, the two cations form a homogeneous mixed phase with the isoorotate ion. Such observation appears in contrast with the Hume-Rothery principles for solid solutions. Furthermore the mixed salts in the series are thermally stable up to 100 8C and non-hygroscopic, which makes them relevant for their potential use as a lithium drug substance. en_US
dc.language.iso eng en_US
dc.publisher Royal Society of Chemistry en_US
dc.relation.ispartofseries Chemical Communications;55, pp. 2297-2300
dc.relation.uri http://dx.doi.org/10.1039/c8cc09850f
dc.subject molecular en_US
dc.subject lithium en_US
dc.subject sodium ions en_US
dc.title A mixed molecular salt of lithium and sodium breaks the Hume-Rothery rules for solid solutions en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1039/c8cc09850f
dc.rights.accessrights info:eu-repo/semantics/openAccess en_US


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