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Reversible switching between highly porous and non-porous phases of an interpenetrated diamondoid coordination network that exhibits gate-opening at methane storage pressures

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dc.contributor.author Yang, Qing‐Yuan
dc.contributor.author Lama, Prem
dc.contributor.author Sen, Susan
dc.contributor.author Lusi, Matteo
dc.contributor.author Chen, Kai-Jie
dc.contributor.author Gao, Wen-Yang
dc.contributor.author Shivanna, Mohana
dc.contributor.author Pham, Tony
dc.contributor.author Hosono, Nobuhiko
dc.contributor.author Kusaka, Shinpei
dc.contributor.author Perry, John J.
dc.contributor.author Ma, Shengqian
dc.contributor.author Space, Brian
dc.contributor.author Barbour, Leonard J.
dc.contributor.author Kitagawa, Susumu
dc.contributor.author Zaworotko, Michael J.
dc.date.accessioned 2018-07-06T11:44:27Z
dc.date.issued 2018
dc.identifier.uri http://hdl.handle.net/10344/6940
dc.description peer-reviewed en_US
dc.description The full text of this article will not be available in ULIR until the embago expires on the 25/03/2019
dc.description.abstract Herein, we report that a new flexible coordination network, NiL2 (L=4‐(4‐pyridyl)‐biphenyl‐4‐carboxylic acid), with diamondoid topology switches between non‐porous (closed) and several porous (open) phases at specific CO2 and CH4 pressures. These phases are manifested by multi‐step low‐pressure isotherms for CO2 or a single‐step high‐pressure isotherm for CH4. The potential methane working capacity of NiL2 approaches that of compressed natural gas but at much lower pressures. The guest‐induced phase transitions of NiL2 were studied by single‐crystal XRD, in situ variable pressure powder XRD, synchrotron powder XRD, pressure‐gradient differential scanning calorimetry (P‐DSC), and molecular modeling. The detailed structural information provides insight into the extreme flexibility of NiL2. Specifically, the extended linker ligand, L, undergoes ligand contortion and interactions between interpenetrated networks or sorbate–sorbent interactions enable the observed switching. en_US
dc.language.iso eng en_US
dc.publisher Wiley and Sons Ltd en_US
dc.relation.ispartofseries Angewandte Chemie;54, pp. 7042-7045
dc.relation.uri http://dx.doi.org/10.1002/anie.201800820
dc.rights This is the peer reviewed version of the following article: Reversible switching between highly porous and non-porous phases of an interpenetrated diamondoid coordination network that exhibits gate-opening at methane storage pressures, Angewandte Chemie;54,pp. 7042-7045 which has been published in final form at http://dx.doi.org/10.1002/anie.201800820 [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. http://olabout.wiley.com/WileyCDA/Section/id-828039.html#terms
dc.subject flexible microporous materials en_US
dc.subject switching en_US
dc.subject stepped adsorption isotherm en_US
dc.subject contortion 4 en_US
dc.subject methane storage en_US
dc.title Reversible switching between highly porous and non-porous phases of an interpenetrated diamondoid coordination network that exhibits gate-opening at methane storage pressures en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1002/anie.201800820
dc.contributor.sponsor SFI en_US
dc.contributor.sponsor National Science Foundation en_US
dc.contributor.sponsor Japan Society of the Promotion of Science en_US
dc.contributor.sponsor Japan Science and Technology Agency en_US
dc.relation.projectid 13/RP/B2549 en_US
dc.relation.projectid CHE-1152362 en_US
dc.relation.projectid TG-DMR090028 en_US
dc.relation.projectid 25000007 en_US
dc.relation.projectid EE16167-1 en_US
dc.date.embargoEndDate 2019-03-25
dc.embargo.terms 2019-03-25 en_US
dc.rights.accessrights info:eu-repo/semantics/embargoedAccess en_US


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