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Specific ion effects on the mediated oxidation of NADH

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Show simple item record Carucci, Cristina Salis, Andrea Magner, Edmond 2018-03-29T08:38:03Z 2017
dc.description peer-reviewed en_US
dc.description.abstract The electrochemical mediated oxidation of dihydronicotinamide adenine dinucleotide (NADH) by 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) was examined in a range of electrolytes. Changes in the Faradaic response were observed that were dependent on the nature of the salt used. In the presence of 200 mM chloride salts, the Faradaic response followed the trend Na+ > K+ > Li+ > Cs+ > Gnd(+) while in the presence of 200 mM sodium salts, the trend Cl- > Br- > F- > ClO4- > SCN- was observed. The observed trends varied when the concentration of the ions was altered. The effect of the cation also changed when the counterion was changed, indicating that specific ion pair effects were present. The results indicate that the nature of the electrolyte alters the Faradaic response. en_US
dc.language.iso eng en_US
dc.publisher Wiley for ChemPubSoc Europe en_US
dc.relation.ispartofseries ChemElectroChem;4 (12), pp. 3075-3080
dc.rights This is the peer reviewed version of the following article:"Specific ion effects on the mediated oxidation of NADH", Cristina Carucci, Andrea Salis, and Edmond Magner,in ChemElectroChem, 2017, 4 (12), pp. 3075-3080 which has been published in final form at en_US
dc.subject Hofmeister en_US
dc.subject NADH en_US
dc.subject ABTS en_US
dc.subject specific ion effect en_US
dc.title Specific ion effects on the mediated oxidation of NADH en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US 2018-03-29T08:20:41Z
dc.description.version ACCEPTED
dc.identifier.doi 10.1002/celc.201700672
dc.contributor.sponsor SFI en_US
dc.relation.projectid 12/RC/2275 en_US
dc.relation.projectid F72F16003070002 en_US 2018-09-16
dc.embargo.terms 2018-09-16 en_US
dc.rights.accessrights info:eu-repo/semantics/embargoedAccess en_US
dc.internal.rssid 2736117
dc.internal.copyrightchecked Yes
dc.identifier.journaltitle Chemelectrochem
dc.description.status peer-reviewed

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