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Electrolyte effects on enzyme electrochemistry

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dc.contributor.author Carucci, Cristina
dc.contributor.author Salis, Andrea
dc.contributor.author Magner, Edmond
dc.date.accessioned 2017-12-12T14:27:04Z
dc.date.issued 2017
dc.identifier.uri http://hdl.handle.net/10344/6349
dc.description peer-reviewed en_US
dc.description.abstract The electrolytes used in enzymatic biosensors or biofuel cells have always been considered to be inert. However, recent studies have demonstrated that this assumption is not correct and that the nature of the electrolyte needs to be considered. Ion specific interactions can occur with the faradaic response observed in both direct and mediated electron transfer being modulated by the nature of the salt used in solution. Specific ion effects arise from the Hofmeister series, which is well established in studies of protein systems but not in electrochemical studies of redox enzymes. Recent experimental and theoretical work on explaining the Hofmeister effect is described en_US
dc.language.iso eng en_US
dc.publisher Elsevier en_US
dc.relation.ispartofseries Current Opinion in Electrochemistry;5 (1), pp. 158-164
dc.relation.uri https://doi.org/10.1016/j.coelec.2017.08.011
dc.rights This is the author’s version of a work that was accepted for publication in Current Opinion in Electrochemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Current Opinion in Electrochemistry, 2017, 5 (1), pp. 158-164, https://doi.org/10.1016/j.coelec.2017.08.011 en_US
dc.subject biofuel cells en_US
dc.subject biochemistry en_US
dc.title Electrolyte effects on enzyme electrochemistry en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1016/j.coelec.2017.08.011
dc.contributor.sponsor SFI en_US
dc.contributor.sponsor Fondazione di Sardegna en_US
dc.relation.projectid 12/RC/2275 en_US
dc.date.embargoEndDate 2019-08-24
dc.embargo.terms 2019-08-24 en_US
dc.rights.accessrights info:eu-repo/semantics/embargoedAccess en_US


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