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Redox electrocatalysis of floating nanoparticles: determining electrocatalytic properties without the influence of solid supports

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dc.contributor.author Peljo, Pekka
dc.contributor.author Scanlon, Micheál D.
dc.contributor.author Olaya, Astrid J
dc.contributor.author Rivier, Lucie
dc.contributor.author Smirnov, Evgeny
dc.contributor.author Girault, Hubert H
dc.date.accessioned 2017-07-26T11:48:08Z
dc.date.issued 2017
dc.identifier.uri http://hdl.handle.net/10344/5916
dc.description peer-reviewed en_US
dc.description.abstract Redox electrocatalysis (catalysis of electron transfer reactions by floating conductive particles) is discussed from the point-of-view of Fermi level equilibration, and an overall theoretical framework is given. Examples of redox electrocatalysis in solution, in bipolar configuration and at liquid-liquid interfaces are provided, highlighting that bipolar and liquid-liquid interfacial systems allow the study of the electrocatalytic properties of particles without effects from the support, but only liquid-liquid interfaces allow measurement of the electrocatalytic current directly. Additionally, photo-induced redox electrocatalysis will be of interest, for example to achieve water splitting en_US
dc.language.iso eng en_US
dc.publisher American Chemical Society en_US
dc.relation.ispartofseries Journal of Physical Chemistry Letters;8, pp. 3564-3575
dc.relation.uri http://dx.doi.org/10.1021/acs.jpclett.7b00685
dc.rights © 2017 ACS This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.jpclett.7b00685 en_US
dc.subject fermi level equilibration en_US
dc.subject floating nanoparticles en_US
dc.subject liquid-liquid interfaces en_US
dc.title Redox electrocatalysis of floating nanoparticles: determining electrocatalytic properties without the influence of solid supports en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.identifier.doi 10.1021/acs.jpclett.7b00685
dc.contributor.sponsor Swiss National Science Foundation en_US
dc.contributor.sponsor SFI en_US
dc.relation.projectid Ambizione Energy 160553 en_US
dc.relation.projectid Solar Fuels 2000-20_152 557/1 en_US
dc.relation.projectid 13/SIRG/2137 en_US
dc.date.embargoEndDate 2018-07-14
dc.embargo.terms 2018-07-14 en_US
dc.rights.accessrights info:eu-repo/semantics/embargoedAccess en_US
dc.internal.rssid 2736309


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