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Spontaneous room temperature elongation of CdS and Ag2S nanorods via oriented attachment

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dc.contributor.author O'Sullivan, Catriona
dc.contributor.author Gunning, Robert D.
dc.contributor.author Sanyal, Ambarish
dc.contributor.author Barrett, Christopher A.
dc.contributor.author Geaney, Hugh
dc.contributor.author Laffir, Fathima R.
dc.contributor.author Ahmed, Shafaat
dc.contributor.author Ryan, Kevin M.
dc.date.accessioned 2013-03-25T15:13:38Z
dc.date.available 2013-03-25T15:13:38Z
dc.date.issued 2009
dc.identifier.uri http://hdl.handle.net/10344/2983
dc.description peer-reviewed en_US
dc.description.abstract Spontaneous elongation from nanorod to nanowire in the presence of an amine is reported for nanocrystals of cadmium sulfide and silver sulfide (cation exchanged from CdS). Elongation occurs instantaneously where the final aspect ratio is a controllable multiple of the original nanorod length. The influential factors on the attachment process are the alkyl-amine chain length, concentration of amine, duration and temperature of the reaction. The nanorods are characterized by high resolution transition electron microscopy (HRTEM), X-Ray diffraction (XRD), photoluminescence (PL), ultraviolet-visible spectroscopy (UV-Vis) and X-ray photoelectron spectroscopy (XPS). A mechanism of oriented attachment is evidenced by the doubling in length of asymmetrically gold tipped CdS nanorods with the corresponding absence of elongation in symmetrically tipped nanorods. en_US
dc.language.iso eng en_US
dc.publisher American Chemical Society en_US
dc.relation.ispartofseries Journal of the American Chemical Society;131(34), pp. 12250-12257
dc.relation.uri http://dx.doi.org/ 10.1021/ja902860t
dc.rights This document is the unedited author's version of a Submitted Work that was subsequently accepted for publication in Journal of the American chemical Society 131(34), pp. 12250-12257 , copyright © American Chemical Society after peer review. To access the final edited and published work, see http://dx.doi.org/ 10.1021/ja902860t en_US
dc.subject nanorods en_US
dc.subject nanowires en_US
dc.subject x-ray diffraction en_US
dc.title Spontaneous room temperature elongation of CdS and Ag2S nanorods via oriented attachment en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.contributor.sponsor SFI en_US
dc.contributor.sponsor IRCSET en_US
dc.relation.projectid 06/IN.1/I85 en_US
dc.rights.accessrights info:eu-repo/semantics/openAccess en_US


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