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Catalytic etherification of 5-hydroxymethylfurfural into 5-ethoxymethy-furfural over sulfated bimetallic SO4 2− /Al-Zr/KIT-6, a Lewis/Brønsted acid hybrid catalyst

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dc.contributor.author Hafizi, Hamid
dc.contributor.author Walker, Gavin M.
dc.contributor.author Iqbal, Javed
dc.contributor.author Leahy, James J.
dc.contributor.author Collins, Maurice N.
dc.date.accessioned 2021-05-14T08:57:26Z
dc.date.available 2021-05-14T08:57:26Z
dc.date.issued 2020
dc.identifier.citation Hafizi H.;Walker G.;Iqbal J.;Leahy J.J.;Collins M.N. (2020) 'Catalytic etherification of 5-hydroxymethylfurfural into 5-ethoxymethyfurfural over sulfated bimetallic SO42â /Al-Zr/KIT-6, a Lewis/Brønsted acid hybrid catalyst'. Journal Of Molecular Catalysis, 496 . en_US
dc.identifier.issn 2468-8231
dc.identifier.uri http://hdl.handle.net/10344/10077
dc.description peer-reviewed en_US
dc.description.abstract .A series of mesoporous composites of SO4 2− /Al-Zr/KIT-6, with varied ratios of ZrO2 to Al2O3 and degrees of sulfation have been synthesized as an efficient, clean, facile and environmental-friendly nano-catalyst for the selective etherification of biomass-derived 5 hydroxymethylfurfural (HMF) to produce 5-ethoxymethylfurfural (EMF) as a biofuel candidate in a one pot process. Structure/property relationships of the catalyst have been determined and optimized in terms of EMF yield and HMF conversion. The resulting catalyst has been further tuned through tailored reaction conditions to produce an EMF yield of 89.8 % and HMF conversion of 99 % en_US
dc.language.iso eng en_US
dc.publisher Elsevier en_US
dc.relation.ispartofseries Molecular Catalysis;496, 111176
dc.relation.uri https://doi.org/10.1016/j.mcat.2020.111176
dc.subject 5-Ethoxymethylfurfural en_US
dc.subject HMF etherification en_US
dc.subject KIT-6 en_US
dc.subject mesoporous silica en_US
dc.subject sulfated bimetallic en_US
dc.title Catalytic etherification of 5-hydroxymethylfurfural into 5-ethoxymethy-furfural over sulfated bimetallic SO4 2− /Al-Zr/KIT-6, a Lewis/Brønsted acid hybrid catalyst en_US
dc.type info:eu-repo/semantics/article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.date.updated 2021-05-14T08:50:13Z
dc.description.version PUBLISHED
dc.identifier.doi 10.1016/j.mcat.2020.111176
dc.identifier.doi 10.1016/j.mcat.2020.111176
dc.rights.accessrights info:eu-repo/semantics/openAccess en_US
dc.internal.rssid 2967760
dc.internal.copyrightchecked Yes
dc.identifier.journaltitle Journal Of Molecular Catalysis
dc.description.status peer-reviewed


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