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Magnetization of electrodeposited nickel : role of interstitial carbon

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dc.contributor.author O'Reilly, Cora
dc.contributor.author Sanvito, Stefano
dc.contributor.author Rhen, Fernando M.F.
dc.contributor.author Stamenov, Plamen
dc.contributor.author Coey, John Michael David
dc.date.accessioned 2010-09-06T16:20:57Z
dc.date.available 2010-09-06T16:20:57Z
dc.date.issued 2006
dc.identifier.uri http://hdl.handle.net/10344/536
dc.description peer-reviewed en_US
dc.description.abstract The magnetization of nickel foils electrodeposited under different conditions was not usually found to differ significantly from that of the bulk (55.4 Am2 kg−1). However, some galvanostatically deposited films from a citrate-based electrolyte showed a lower magnetization, which was rose to the bulk value after annealing at 575 K, with no change in lattice parameter. Analysis of the influence of various lattice defects (nickel vacancies or interstitials, hydrogen or carbon impurities) using density functional theory indicates that nickel vacancies may be present in all of the films and that a nonequilibrium concentration of carbon interstitials is the likely explanation of the reduced magnetization in the citrate as-deposited nickel. en_US
dc.language.iso eng en_US
dc.publisher American Institute of Physics en_US
dc.relation.ispartofseries Journal of Applied Physics;99/ 08J301
dc.relation.uri http://dx.doi.org/10.1063/1.2162508
dc.subject magnetization en_US
dc.title Magnetization of electrodeposited nickel : role of interstitial carbon en_US
dc.type Journal Article en_US
dc.type.supercollection all_ul_research en_US
dc.type.supercollection ul_published_reviewed en_US
dc.type.restriction none en
dc.contributor.sponsor SFI

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